AUGUST 2005
LITHIUM HANDBOOK
This information is generally descriptive only and is not intended to make or imply any representation, guarantee or warranty with respect to any cells and batteries. Cell and battery designs/specifications
are subject to modification without notice. Contact Panasonic for the latest information.
Manganese Lithium Coin Batteries (ML series): Individual Specifications
ML2020
Duration (days)
10000
5000
1000
500
100
50
10
11 5 10 50 100 500 1000 5000 1000
0
Consumption Current (µA)
0 10 20 30 40 50 6
0
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
20k
(120 A)
Temp
Load
Discharge capacity(mAh)
Voltage(V)
Dimensions(mm)
Specification
Discharge characteristics
Consumption current vs. Duration time
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
3
45
0.12
-20 ~ +60
Weight:2.2g
Note: This bare cell diagram is for size reference only. Please refer to the
tab configurations at the end of this section for available tabs.
20.0
+
-
0
0.3
( 0.79 )
+
-
0
0.01
0.05(0.002)
2.0
+
-
0
0.3
(0.08 )
+
-
0
0.01
16( 0.63)
0
.3MAX
(
0.012)
AUGUST 2005
LITHIUM HANDBOOK
This information is generally descriptive only and is not intended to make or imply any representation, guarantee or warranty with respect to any cells and batteries. Cell and battery designs/specifications are subject to
modification without notice. Contact Panasonic for the latest information.
ML414
2.5 2.6 2.7 2.8 2.9 3.0 3.1 3.2 3.3 3.4 3.5
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0
Temp: 20˚C
Load: 300k
Cut off voltage 2.0V
Charge Voltage (V)
Discharge Capacity (mAh)
ML421
4.8
4.0 (max)
1.45
0.02
(min)
+0
-0.15
+0
-0.15
4.8
4.0 ± 0.3
2.15
0.05
(min)
+0
-0.15
+0
-0.15
0 0.5 1.0 1.5
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
Temp: 20˚C
Load: 300k (8µA)
Discharge Capacity (mAh)
Voltage (V)
0.0 0.5 1.0 1.5 2.0 2.5 3.0
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
Temp: 20˚C
Load: 1M (2.5µA)
Discharge Capacity (mAh)
Voltage (V)
Dimensions(mm)
Specification
Discharge characteristics
Dimensions(mm)
Specification
Discharge characteristics
Consumption current vs. Duration time Consumption current vs. Duration time
Weight 0.09g Weight 0.11g
Manganese Lithium Coin Batteries (ML series): Individual Specifications
2.6 2.7 2.8 2.9 3.0 3.1 3.2 3.3 3.4
3.0
2.5
2.0
1.5
1.0
0.5
0.0
Temp: 20˚C
Load: 1M
Cut off voltage: 2.0V
Charge Voltage (V)
Discharge Capacity (mAh)
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
3
2.3
0.003
-20 ~ +60
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
3
1.2
0.005
-20 ~ +60
AUGUST 2005
LITHIUM HANDBOOK
This information is generally descriptive only and is not intended to make or imply any representation, guarantee or warranty with respect to any cells and batteries. Cell and battery designs/specifications are subject to
modification without notice. Contact Panasonic for the latest information.
ML621
Consumption current vs. Duration time
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
60 C
20 C
-20 C
load: 200k
(12µA)
Charge characteristics : 3.1V, 1k, 45hrs
Discharge capacity(mAh)
Voltage(V)
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0
3.1V
ML621S
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
Voltage
Current
hour(h)
Current(mA)
Voltage(V)
0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 50.0
Duration (days)
1 5 10 50 100 500 1000 5000 10000
10000
5000
1000
500
100
50
10
1
Consumption Current (µA)
6.8
5.2 (max)
2.15
0.05
(min)
+0
-0.15
+0
-0.20
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
Dimensions(mm)
Specification
Discharge characteristics
Charge characteristics
3
5
0.01
-20 ~ +60
Weight:0.23g
Note: This bare cell diagram is for size reference only. Please refer to the
tab configurations at the end of this section for available tabs.
ML614
Duration(days)
1 5 10 50 100 500 1000 5000 10000
10000
5000
1000
500
100
50
10
1
Consumption Current (µA)
6.8
5.0 ± 0.3
1.45
0.05
(min)
+0
-0.15
+0
-0.15
0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
300k
(8 A)
Temp
Load
Discharge capacity(mAh)
Voltage(V)
Dimensions(mm)
Specification
Discharge characteristics
Consumption current vs. Duration time
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
3
3.4
0.01
-20 ~ +60
Weight:0.16g
Note: This bare cell diagram is for size reference only. Please refer to the
tab configurations at the end of this section for available tabs.
Manganese Lithium Coin Batteries (ML series): Individual Specifications
AUGUST 2005
LITHIUM HANDBOOK
This information is generally descriptive only and is not intended to make or imply any representation, guarantee or warranty with respect to any cells and batteries. Cell and battery designs/specifications are subject to
modification without notice. Contact Panasonic for the latest information.
ML920
Duration(days)
10000
5000
1000
500
100
50
10
11 5 10 50 100 500 1000 5000 10000
Consumption Current (µA)
0 2 4 6 8 10 12 14
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
75k
(32 A)
Temp
Load
Discharge capacity(mAh)
Voltage(V)
Dimensions(mm)
Specification
Discharge characteristics
Consumption current vs. Duration time
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
3
11.0
0.03
-20 ~ +60
Weight:0.4g
Note: This bare cell diagram is for size reference only. Please refer to the
tab configurations at the end of this section for available tabs.
5.0
2.05
0.05
9.5
+0
-0.15
+0
-0.2
Manganese Lithium Coin Batteries (ML series): Individual Specifications
12.5
( 0.49
)
9( 0.35)
2.0
+
-
0
0.3
0.3(0.012)
+0
-0.01
+0
-0.3
Dimensions(mm)
Weight:0.8g
ML1220
Duration(days)
10000
5000
1000
500
100
50
10
11 5 10 50 100 500 1000 5000 10000
Consumption Current (µA)
0 2 4 6 8 10 12 14 16 18 20
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
100k
(24 A)
Temp
Load
Discharge capacity(mAh)
Voltage(V)
Consumption current vs. Duration time
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
Specification
Discharge characteristics
3
17.0
0.03
-20 ~ +60
Note: This bare cell diagram is for size reference only. Please refer to the
tab configurations at the end of this section for available tabs.
Notice: The information and recommendations set forth are made in good faith and are believed to be accurate at the date of preparation.
Panasonic Industrial Company makes no warranty expressed or implied.
053-13 Page 1 of 2
Panasonic Batteries
Panasonic Industrial Company
A Division Panasonic Corporation of North America
5201 Tollview Drive, 1F-3
Rolling Meadows, IL 60008
Toll Free: 877-726-2228
Fax: 847-637-4660
Internet: www.panasonic.com/industrial/batteries.oem
e-mail: oembatteries@panasonic.com
MSDS
Material Safety Data Sheets (MSDS) are a sub-requirement of the Occupational Safety and Health Administration
(OSHA) Hazard Communication Standard, 29 CFR Subpart 1910.1200. This Hazard Communication Standard does
not apply to various subcategories including anything defined by OSHA as an "article". OSHA has defined "article" as a
manufactured item other than a fluid or particle; (i) which is formed to a specific shape or design during manufacture; (ii)
which has end use function(s) dependent in whole or in part upon its shape or design during end use; and (iii) which
under normal conditions of use does not release more than very small quantities, e.g. minute or trace amounts of a
hazardous chemical, and does not pose a physical hazard or health risk to employees.
Because all of our batteries are defined as "articles", they are exempt from the requirements of the Hazard
Communication Standard; hence a MSDS is not required.
DISPOSAL
These batteries contain so little lithium that they are never defined by the federal government as a reactive hazardous
waste and are safe for disposal in the normal municipal waste stream..
TRANSPORTATION
All Panasonic lithium batteries are not subject to the requirements of the Department of Transportation (DOT)
Subchapter C, Hazardous Materials Regulations if shipped in compliance with 49 CFR 173.185 and Special
Provision 188.
Effective January 1, 2014 all Panasonic lithium batteries can be shipped by air in accordance with International Civil
Aviation Organization (ICAO), 2013-2014 edition, Section II or Section 1B, International Air Transport Association
(IATA) 55th
edition, Section II or Section 1B Packing Instructions (PI) 968 (Batteries), PI 969 (Batteries, packed with
equipment) and PI 970 (Batteries, contained in equipment) as appropriate
All Panasonic lithium batteries are regulated by the International Maritime Organization (IMO), 2012 edition, 36
th
amendment, under Special Provisions 188 and 230.
All Panasonic lithium cells are tested and comply with the UN Model Regulations, Manual of Test and Criteria, Part
III, subsection 38.3.
If you build any of our lithium cells into a battery pack, you must also assure that they are tested in accordance with
the UN Model Regulations, Manual of Test and Criteria. Part III, subsection 38.3, 5
th
revised edition, Amendment 1.
The DOT requires that the outside of each package that contains lithium metal batteries, regardless of size or
number of batteries, be labeled with the following statement: LITHIUM METAL BATTERIES- FORBIDDEN FOR
TRANSPORT ABOARD PASSENGER AIRCRAFT. The labeling requirement covers shipments via highway, rail,
vessel or cargo-only aircraft and covers all shipments inside, into or out of the US. The label must be in contrasting
color and the letters must be 12 mm (0.5 in) in height for packages weighing more than 30 Kg and 6 mm (0.25 in) in
height for packages weighting less than 30 Kg.
Product Information Sheet
:
Manganese
Lithium
(
M
L
Type) Lithium Batteries
Applicable models/sizes: All ML type
Revision: January 1, 2014
The batteries referenced herein are exempt articles and are
not
subject t
o the OSHA Hazard
Communication Standard requirement. This sheet is provided as a service to our customers.
Notice: The information and recommendations set forth are made in good faith and are believed to be accurate at the date of preparation.
Panasonic Industrial Company makes no warranty expressed or implied.
053-13 Page 2 of 2
First Aid
If you get electrolyte in your eyes, flush with water for 15 minutes without rubbing and immediately contact a
physician. If you get electrolyte on your skin wash the area immediately with soap and water. If irritation continues,
contact a physician. If a battery is ingested, call the National Capital Poison Center (NCPC) at 202-625-3333
(Collect) or your local poison center immediately. Lithium coin batteries lodged in the esophagus should be
removed immediately. Leakage, chemical burns and perforation can occur within hours of ingestion.
General Recommendations
CAUTION: Risk of fire, explosion and burns. Do not recharge, crush, heat above 212
O
F (100
O
C) or incinerate.
Fire Safety
In case of fire, you can use a Class “D” fire extinguisher or other smothering agent such as Lith-X, copper powder or dry
sand. If you use water, use enough to smother the fire. Using an insufficient amount of water will only make the fire
worse. Cooling the exterior of the batteries will help prevent rupturing. Burning of these batteries will generate toxic
and corrosive lithium hydroxide fumes. Fire fighters should use self-contained breathing apparatus. Detailed
information on fighting a lithium metal battery fire can be found in Guide 138 (Substances – Water Reactive) of the
US DOT Emergency Response Guide.