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SPECIFICATION 55A, ISSUE 4 Page 15 of 18
4.6.7 Fluoride Extraction
Approximately 0.5 gram of insulation or jacket material shall be removed, cut into 3-inch
(76-mm) lengths, and weighed to the nearest milligram. A polystyrene test tube (without its
cap) shall also be weighed to the nearest 0.1 gram. After filling with approximately 14 ml of
distilled water, the polystyrene test tube shall be reweighed. The insulation or jacket sample
shall then be placed into the test tube, making sure that the sample is fully submerged, and the
test tube cap is tightly attached. The test tube shall then be partially immersed in a 70 ± 2°C
water bath so that the water levels of the bath and the test tube are equal. The test tube shall
be so conditioned for 168 hours with the set-up being periodically checked to make sure that
the sample is still submerged. After conditioning, the test tube shall be removed from the bath
and allowed to cool. The cap shall then be removed from the test tube, and the tube, water and
sample shall be weighed to determine the water weight loss. If the water loss is more than 0.5
gram, the test shall be rerun. Otherwise, 5 ml of the test tube water shall be analyzed for
fluoride ion content using an Ion Chromatograph. The fluoride ion content shall be reported in
ppm of water.
A blank test in accordance with 4.6.7.1 should also be conducted in case the result is needed
for calculation purposes.
4.6.7.1 Blank Test
A blank test follows the same procedure as 4.6.7 except that a specimen is not included. What
is tested is the distilled water and the sample tube. Ideally, there are no fluoride ions in either
the test tube or the distilled water such that the result for the blank test would be zero.
However, there may be a low non-zero result (i.e. 0.005 ppm). If this occurs, the ppm of
fluoride for the blank test must be subtracted from the ppm of fluoride obtained from the
specimen. A blank test also performs the same function as a calibration as it can indicate a
problem with the test procedure. For example, should the blank test produce a result of 15
ppm of fluoride, this would be an indication that the ion chromatograph is not functioning
correctly, tap water was used in place of distilled water, etc.
4.6.7.2 Calculation
If necessary, the blank test result shall be subtracted from the sample result to obtain the net
fluoride ion content (ppm). The fluoride ion content, of the insulation or jacket weight, shall
then be calculated as follows:
F ion = Net F ion (ppm) x Original water weight / Sample weight
4.6.8 Jacket Concentricity
The concentricity of the cable jacket shall be determined by first locating and recording the
minimum wall thickness measured on a cross section of the jacket. The maximum wall
thickness of this same cross section of the jacket shall be measured and recorded. The ratio of
the minimum wall thickness to the maximum wall thickness shall define the concentricity. All
wall thickness measurements shall be made under suitable magnification. The wall thickness
shall be the radial distance between the inner and outer rim of the jacket.